Abdulrahman Bashir doubled the lead for the hosts Enyimba when he headed in Andrew Abalogu’s freekick in the 54th minute.
Sasere Franklin put Sunshine Stars ahead four minutes into the break with a lovely lob from the edge of the box.
But Kwara United were back on level terms through an own goal from Seun Olulayo who diverted Usman Mohammed’s cross beyond his own goalkeeper with 20 minutes to play.
In another NPFL game Nasarawa United beat Abia Warriors 1-0 in Lafia.
Abdullahi Abubakar glided in Abdul Makama’s cross after 20 minutes to hand Nasarawa United all three points from the encounter.
Akwa United who recruited 13 new players kicked off their new NPFL season on a poor note, going down 1-0 at home to El Kanemi Warriors at the Akwa Ibom international Stadium.
Kano Pillars also edged Heartland of Owerri 1-0.
Chinese Sunday scored the only goal of the game in the 16th minute to hand the Sai Masu Gida side maximum points.
Plateau United were held to a goalless draw at home by FC IfeanyiUbah.
NPFL Match day 1 full result:
Kwara Utd 1-1 Sunshine Stars
Enyimba 2-0 MFM
Nasarawa Utd 1-0 Abia Warriors
Plateau Utd 0-0 FC Ifeanyi Ubah
Kano Pillars 1-0 Heartland
Akwa Utd 0-1 El-Kanemi.